解永树，教授, 博士生导师
教育部新世纪优秀人才 (2011)，上海市特聘教授 (2011)，上海市浦江人才 (2008)，上海市优秀学术带头人(2020)。
电话：021-64253530
E-mail: yshxie@ecust.edu.cn
课题组主页：https://www.x-mol.com/groups/Yongshu_Xie
解永树，1971年9月出生于安徽庐江。1998年于浙江大学化学系获博士学位，导师为林瑞森教授。同年到中国科技大学化学系刘清亮教授研究组从事博士后研究。2000 年7月留校任副教授。2003 年至 2007 年间，先后到台湾大学彭旭明教授研究组，日本九州大学古田弘幸(Hiroyuki Furuta) 教授研究组以及日本国立材料研究所有贺克彦(Katsuhiko Ariga) 与Jonathan P. Hill 教授研究组作访问研究。2007 年 8 月回国，被聘为华东理工大学化学与分子工程学院教授，现为“精细合成化学与分子工程”硕士点导师组组长。
针对新型卟啉结构的创制与功能化、光谱与分子间聚集调控等问题,开展系统研究，建立了新型卟啉合成策略，丰富其光谱调控手段，拓展其聚集性能调控途径，实现了碘电解质染料敏化电池的最高光电转换效率,先后获美国发明专利授权 2 项，目前负责国家自然科学基金重点项目、面上项目和上海市优秀学术带头人等项目，现为 Chin. Chem. Lett. 高级编委。
主要研究方向:
1、精细有机合成：设计、合成新型有机光电功能分子，应用于荧光探针和光电转换等领域。
2、新型卟啉研究：基于 “生命色素” 卟啉，开展功能导向的新型卟啉研究，应用于太阳能电池等领域。
近年来发表的部分论文：
1) Kaiwen Zeng, Zhangfa Tong, Lin Ma, Wei-Hong Zhu, Wenjun Wu and Yongshu Xie*, Molecular engineering strategies for fabricating efficient porphyrin-based dye-sensitized and other type solar cells, Energy & Environmental Science, 2020, 13, 1617-1657.
2) Yubin Ding, Wei-Hong Zhu, and Yongshu Xie*, Development of ion sensors based on porphyrin analogues, Chem. Rev., 2017, 117, 2203−2256.
3) Yubin Ding, Yunyu Tang, Weihong Zhu, and Yongshu Xie*, Fluorescent and colorimetric ion probes based on conjugated oligopyrroles, Chem. Soc. Rev., 2015, 44, 1101–1112.
4) Kaiwen Zeng, Yingying Chen, Wei-Hong Zhu, He Tian, and Yongshu Xie*, Efficient Solar Cells based on Concerted Companion Dyes Containing Two Complementary Components: An Alternative Approach for Cosensitization, J. Am. Chem. Soc., 2020, 142 (11), 5154-5161.
5) Chengjie Li, Qizhao Li, Jiewei Shao, Zhangfa Tong, Masatoshi Ishida, Glib Baryshnikov, Hans Ågren, Hiroyuki Furuta*, and Yongshu Xie*, Expanded N-Confused Phlorin: A Platform for Multiply Fused Polycyclic Ring System via Oxidation within the Macrocycle, J. Am. Chem. Soc., 2020, 142, 17195-17205.
6) Qizhao Li, Chengjie Li, Glib Baryshnikov, Yubin Ding, Chengxi Zhao, Tingting Gu, Feng Sha, Xu Liang, Weihua Zhu, Xinyan Wu, Hans Ågren, Jonathan L. Sessler*, Yongshu Xie*, Twisted-Planar-Twisted expanded porphyrinoid dimer as a rudimentary reaction-based methanol indicator, Nature Commun., 2020, 11, 5289.
7) Guangxian Su, Qizhao Li, Masatoshi Ishida, Chengjie Li, Feng Sha, Xin-Yan Wu, Lu Wang,Glib Baryshnikov, Dawei Li, Hans Ågren, Hiroyuki Furuta,* and Yongshu Xie*, N-Confused Phlorin-Prodigiosin Chimera: meso-Aryl Oxidation and p-Extension Triggered by Peripheral Coordination, Angew. Chem. Int. Ed., 2020, 59(4), 1537-1541.
8) Qizhao Li, Chengjie Li, Jinseok Kim, Masatoshi Ishida, Xin Li, Tingting Gu, Xu Liang, Weihua Zhu, Hans Ågren, Dongho Kim,*, Hiroyuki Furuta,* and Yongshu Xie*, Regioselectively Halogenated Expanded Porphyrinoids as Building Blocks for Constructing Porphyrin−Porphyrinoid Heterodyads with Tunable Energy Transfer, J. Am. Chem. Soc., 2019, 141, 5294–5302.
9) Qizhao Li, Masatoshi Ishida, Hiroto Kai, Tingting Gu, Chengjie Li, Xin Li, Glib Baryshnikov, Xu Liang, Weihua Zhu, Hans Ågren, Hiroyuki Furuta*, Yongshu Xie*, Thiophene‐Cleavage‐Triggered Skeletal Rearrangement of a Twisted Thia‐norhexaphyrin towards Multiply‐Annulated Polypyrrolic Aromatic Macrocycles, Angew. Chem. Int. Ed., 2019, 58, 5925–5929.
10) Miao Li, Pingchun Wei, Masatoshi Ishida, Xin Li, Mathew Savage, Rui Guo, Zhongping Ou, Sihai Yang, Hiroyuki Furuta,* and Yongshu Xie*, Macrocyclic transformations from norrole to isonorrole and an N-confused corrole with a fused hexacyclic ring triggered by a pyrrole substituent, Angew. Chem. Int. Ed., 2016, 55, 3063.
11) Yongshu Xie*, Yunyu Tang, Wenjun Wu, Yueqiang Wang, Jingchuan Liu, Xin Li, He Tian, and Wei-Hong Zhu*, Porphyrin cosensitization for a photovoltaic efficiency of 11.5%: a record for non-ruthenium solar cells based on iodine electrolyte, J. Am. Chem. Soc., 2015, 137, 14055–14058.
12) Andong Shao, Yongshu Xie, Shaojia Zhu, Zhiqian Guo,* Shiqin Zhu, Jin Guo, Ping Shi, Tony D. James, He Tian, and Wei-Hong Zhu*, Far-red and near-IR AIE-active fluorescent organic nanoprobes with enhanced tumor-targeting efficacy: shape-specific effects, Angew. Chem. Int. Ed., 2015, 54(25), 7275-7280.
13) Yueqiang Wang, Bin Chen, Wenjun Wu, Xin Li, Weihong Zhu, He Tian and Yongshu Xie*, Efficient solar cells sensitized by porphyrins with an extended conjugation framework and a carbazole donor: from molecular design to cosensitization, Angew. Chem. Int. Ed., 2014, 53, 10779–10783.
14) Pingchun Wei, Kai Zhang, Xin Li, Deying Meng, Hans Ågren, Zhongping Ou, Seikweng Ng, Hiroyuki Furuta*, and Yongshu Xie*, Neo-fused hexaphyrin: a molecular puzzle containing an N-linked pentaphyrin, Angew. Chem. Int. Ed., 2014, 53, 14069–14073.
15) Yue Wu, Yongshu Xie, Qiong Zhang, He Tian, Weihong Zhu*, Alexander D. Q. Li*, Quantitative photoswitching in bis(dithiazole)ethene enables modulation of light for encoding optical signals, Angew. Chem., Int. Ed., 2014, 53, 2090–2094.
16) Wenlong Li, Changhong Jiao, Xin Li, Yongshu Xie, Keitaro Nakatani, He Tian, Weihong Zhu*, Separation of photoactive conformers based on hindered diarylethenes: efficient modulation in photocyclization quantum yields, Angew. Chem. Int. Ed., 2014, 53, 4603–4607.
17) Yongshu Xie*, Pingchun Wei, Xin Li, Tao Hong, Kai Zhang, and Hiroyuki Furuta*, Macrocycle contraction and expansion of a dihydrosapphyrin isomer, J. Am. Chem. Soc., 2013, 135, 19119–19122.
18) Zhiyun Zhang, Bo Xu, Jianhua Su, Leiping Shen, Yongshu Xie, He Tian*, Color-tunable solid-state emission of 2,2'-biindenyl-based fluorophores, Angew. Chem. Int. Ed., 2011, 50, 11654–11657.
19) Weihong Zhu*, Yuheng Yang, Rémi Métivier, Qiong Zhang, Régis Guillot, Yongshu Xie, He Tian, Keitaro Nakatani*, Unprecedented stability of a photochromic bisthienylethene based on benzobisthiadiazole as an ethene bridge, Angew. Chem. Int. Ed. 2011, 50, 10986–10990.
20) Yongshu Xie, Keisuke Yamaguchi, Motoki Toganoh, Hidemitsu Uno, Masaaki Suzuki, Shigeki Mori, Shohei Saito, Atsuhiro Osuka*, Hiroyuki Furuta*, Triply N-confused hexaphyrins: near-infrared luminescent dyes with a triangular shape, Angew. Chem. Int. Ed., 2009, 48, 5496–5499.
21) Francis D’Souza*, N. K. Subbaiyan, Yongshu Xie, Jonathan P. Hill*, Katsuhiko Ariga, Kei Ohkubo, and Shunichi Fukuzumi*, Anion-complexation-induced stabilization of charge separation, J. Am. Chem. Soc., 2009, 131, 16138–16146.
22) Yongshu Xie, Tatsuki Morimoto, Hiroyuki Furuta*, SnIV complexes of N-confused porphyrins and oxoporphyrins - Unique fluorescence Switch-On halide receptors, Angew. Chem. Int. Ed., 2006, 45, 6907–6910.
23) Chengjie Li, Kai Zhang, Masatoshi Ishida, Qizhao Li, Keito Shimomura, Glib Baryshnikov, Xin Li, Mathew Savage, Xin-Yan Wu, Sihai Yang, Hiroyuki Furuta,* and Yongshu Xie*, Tripyrrin-Armed Isosmaragdyrins: Synthesis, Heterodinuclear Coordination, and Protonation-Triggered Helical Inversion, Chem. Sci., 2020, 11, 2790-2795.
24) Kaiwen Zeng, Yunyue Lu, Weiqiang Tang, Shuangliang Zhao, Qingyun Liu, Weihong Zhu, He Tian, and Yongshu Xie*, Efficient solar cells sensitized by a promising new type of porphyrins: dye-aggregation suppressed by double strapping, Chem. Sci., 2019, 10, 2186-2192.
25) Yongshu Xie, Wenjun Wu, Haibo Zhu, Jingchuan Liu, Weiwei Zhang, He Tian, and Wei-Hong Zhu*, Unprecedentedly targeted customization of molecular energy levels with auxiliary-groups in organic solar cell sensitizers, Chem. Sci., 2016, 7, 544-549.
26) Jiazhi Zou, Yunyu Tang, Glib Baryshnikov, Zhen Yang, Rui Mao, Weifang Feng, Jian Guan, Chengjie Li*, Yongshu Xie*, Porphyrins containing a tetraphenylethylene-substituted pheno-thiazine donor for fabricating efficient dye sensitized solar cells with high photovoltages, J. Mater. Chem. A, 2022, 10, 1320-1328.
27) Xueyan Wang, Yuqing Wang, Jiazhi Zou, Jiaxin Luo, Chengjie Li,* Yongshu Xie*, Efficient Solar Cells Sensitized by Organic Concerted Companion Dyes Suitable for Indoor Lamps, ChemSusChem, 2022, e202201116.
28) Yue Xu, Bin Zhu, Qizhao Li,* Glib Baryshnikov, Mingbo Zhou, Chengjie Li, Feng Sha, Xinyan Wu, Hans Ågren, Jianxin Song, and Yongshu Xie*, Confusion Approach Modulated Syntheses of Corrorin Parasitized Hexaphyrins(1.1.1.1.1.0) and the Oxidative Ring Cleavage Behavior, Org. Lett., 2021, 23, 8307-8311.
29) Yingying Chen,# Yunyu Tang,# Jiazhi Zou, Kaiwen Zeng, Glib Baryshnikov, Chengjie Li,* and Yongshu Xie*, Fluorenyl Indoline as an Efficient Electron Donor for Concerted Companion Dyes: Enhanced Light-Harvesting and Photocurrent, ACS Appl. Mater. Interfaces, 2021, 13, 49828−49839.
30) Yunyu Tang, Xiujun Liu, Yueqiang Wang, Qingyun Liu,* Xin Li, Chengjie Li, Xiaosheng Shen,* Yongshu Xie*, Solar cells sensitized by porphyrin dyes containing a substituted carbazole donor with synergistically extended absorption and suppressed the dye aggregation, Chin. Chem. Lett., 2020, 31, 1927–1930.
31) Jiazhi Zou, Qifan Yan, Chengjie Li, Yunyue Lu, Zhangfa Tong, Yongshu Xie*, Light-Absorbing Pyridine Derivative as a New Electrolyte Additive for Developing Efficient Porphyrin Dye-Sensitized Solar Cells, ACS Applied Materials & Interfaces, 2020, 12 (51), 57017-57024.
32) Yu Du, Bin Zhu, Qizhao Li,* Glib Baryshnikov, Chuanwan Wei, Yingwu Lin, Guangxian Su, Chengjie Li, Hans Ågren, and Yongshu Xie*, N-Confused Hexapyrrolic Phlorinoid with NIR Absorption: Synthesis, Fusion, Oxidation, and Copper(II) Coordination, Org. Lett., 2020, 22, 9648-9652.
33) Yunyue Lu, Heli Song, Xin Li, Hans Ågren, Qingyun Liu, Jiwei Zhang, Xuan Zhang,* Yongshu Xie*, Multiply Wrapped Porphyrin Dyes with a Phenothiazine Donor: A High Efficiency of 11.7% Achieved through a Synergetic Coadsorption and Cosensitization Approach, ACS Applied Materials & Interfaces, 2019, 11, 5046-5054.
34) Yunyue Lu, Qingyun Liu, Jiaxin Luo, Bo Wang, Tong Feng, Xiaoyi Zhou, Xinyu Liu, Yongshu Xie*, Solar Cells Sensitized with Porphyrin Dyes Containing Oligo(Ethylene Glycol) Units: a High Efficiency Beyond 12%, ChemSusChem, 2019, 12, 2802-2809.
35) Fangtao Ma, Li Zhou, Qingyun Liu, Chengjie Li*, and Yongshu Xie*, Selective Photocatalysis Approach for Introducing ArS Units into BODIPYs through Thiyl Radicals, Org. Lett., 2019, 21(3), 733–736.
36) Yingchun Cheng, Guosheng Yang, Haoran Jiang, Shuangliang Zhao, Qingyun Liu, Yongshu Xie*, Organic Sensitizers with Extended Conjugation Frameworks as Cosensitizers of Porphyrins for Developing Efficient Dye-Sensitized Solar Cells. ACS Applied Materials & Interfaces, 2018, 10, 38880-38891.
37) Heli Song, Jing Zhang, Jiamin Jin, Haifeng Wang, and Yongshu Xie*, Porphyrin Sensitizers with Modified Indoline Donors for Dye-Sensitized Solar Cells, J. Mater. Chem. C, 2018, 6 (15), 3927-3936.
38) Jiewei Shao, Chengjie Li,*, Jiahui Kong, Haoran Jiang, Shuangliang Zhao, Minzhi Li, Xu Liang, Weihua Zhu, and Yongshu Xie*, Regioselective Oxidative Ring Cleavage of a Phlorin Analogue: an Approach for Synthesizing Linear Tetrapyrroles, Org. Lett., 2018, 20(7), 1941-1944.
39) Heli Song, Qingyun Liu, Yongshu Xie*, Porphyrin-sensitized solar cells: systematic molecular optimization, coadsorption and cosensitization, Chem. Commun., 2018, 54, 1811-1824.
40) Guosheng Yang, Yunyu Tang, Xin Li, Hans Ågren, and Yongshu Xie*, Efficient Solar Cells Based on Porphyrin Dyes with Flexible Chains Attached to the Auxiliary Benzothiadiazole Acceptor: Suppression of Dye Aggregation and the Effect of Distortion, ACS Appl. Mater. Interfaces, 2017, 9 (42), 36875–36885.