曲大辉


曲大辉，教授，博士生导师

联系电话：021-64252759

Email：dahui_qu@ecust.edu.cn

办公室：实验十三楼407

学术学位研究生招生专业：应用化学、精细合成化学与分子工程

专业学位研究生招生专业：材料与化工、生物与医药

个人简介

曲大辉， 教授、博士生导师。于2000 年在青岛大学获得学士学位，先后于2003年和2006年在华东理工大学获硕士、博士学位，2006年至2009年在荷兰格罗宁根大学从事博士后研究。2009年2月起在华东理工大学化学与分子工程学院任教，历任讲师、副教授、教授。

研究领域与主要学术成绩

   主要从事动态化学与智能分子材料领域的研究。围绕动态分子基元设计和组装策略以及高性能动态材料的高效创制等关键问题，利用天然硫辛酸动态基元和机械互锁动态基元的结构独特性、动态性，创新了非共价键、动态共价键以及机械互锁相互作用等多级协同、动态组装策略，发展了一系列分子机器智能组装材料以及动态发光材料，实现了聚硫辛酸高性能动态聚合物材料的简单、高效制备，为智能分子材料的设计和高效、绿色创制提供了新思路。已发表SCI收录论文130余篇，其中通讯和一作论文110余篇，SCI引用共计5500余次。近五年以通讯作者发表论文70余篇，其中包括CCS Chem (3), Nat. Sci. Rev., Chem (2), Matter (3), Nat. Commun. (2), Sci. Adv. (2), J. Am. Chem. Soc. (6), Angew. Chem. Int. Ed. (7), Adv. Mater. (2)等期刊上发表论文28篇，获授权发明专利9项。撰写英文专著3个章节。曾获国家杰出青年科学基金（2020年）、上海市优秀学术带头人（2019年）、上海市浦江人才计划、上海市晨光学者、教育部霍英东青年教师基金等人才计划或者项目资助，入选英国皇家化学会会士（FRSC）等。曾获“全国优秀博士学位论文”、上海市自然科学奖二等奖（2020年，第一完成人）、中国化学会超分子化学青年创新学术讲座奖（2021年）等奖励及荣誉，连续入选2020-2022年Elsevier高被引学者。担任国际期刊Frontier in Chemistry（IF 5.1）副主编，Chin. Chem. Lett. 编委等。

近五年代表性论文

  1. Tianyi Xu, Fei Tong*, Hui Xu, Meng-Qi Wang, He Tian, Da-Hui Qu*, Engineering Photomechanical Molecular Crystals to Achieve Extraordinary Expansion Based on Solid-State [2+2] Photocycloaddition. J. Am. Chem. Soc.2022, 144, 6278-6290.

  2. Huiting Yang, Jinhao Yi, Shihao Pang, Kai Ye, Zhicheng Ye, Qi Duan, Zexin Yan, Cheng Lian, Yi Yang, Linyong Zhu, Da-Hui Qu*, Chunyan Bao*, A Light-Driven Molecular Machine Controls K+ Channel Transport and Induces Cancer Cell Apoptosis. Angew. Chem. Int. Ed.2022, 61, e202204605.

  3. Qi Zhang, Stefano Crespi, Ryojun Toyoda, Romain Costil, Wesley R. Browne, Da-Hui Qu*, He Tian, Ben L. Feringa*, Stereodivergent Chirality Transfer by Noncovalent Control of Disulfide Bonds. J. Am. Chem. Soc.2022, 144, 4376-4382.

  4. Qi Zhang, Da-Hui Qu*, Ben L. Feringa, He Tian*, Disulfide-Mediated Reversible Polymerization toward Intrinsically Dynamic Smart Materials. J. Am. Chem. Soc.2022, 144, 2022-2033.

  5. Yuan-Xin Deng, Qi Zhang, Chen-Yu Shi, Ryojun Toyoda, Da-Hui Qu*, He Tian, Ben L. Feringa*, Acylhydrazine-Based Reticular Hydrogen Bonds Enable Robust, Tough and Dynamic Supramolecular Materials. Sci. Adv.2022, 8, eabk3286.

  6. Ze-Zhou Zong, Qi Zhang, Shu-Hai Qiu, Qian Wang, Cheng-Xi Zhao, Cai-Xin Zhao, He Tian, Da-Hui Qu*, Dynamic Timing Control over Multicolor Molecular Emission by Temporal Chemical Locking. Angew. Chem. Int. Ed.2022, 61, e202116414.

  7. Shang-Wu Zhou, Fei Tong, Meng Chen, Rui-Rui Gu, Chen-Yu Shi, Cheng-Yuan Yu, Qi Zhang, Da-Hui Qu*, Self-Evolution of High Mechanical Strength Dry-Network Polythiourethane Thermosets into Neat Macroscopic Hollow Structures. Angew. Chem. Int. Ed.2022, 61, e202117195.

  8. Yunpeng Li, Chengxi Zhao, Rui Wang, Ajun Tang, Wenjing Hong, Da-Hui Qu*, He Tian and Hongxiang Li*, In Situ Monitoring of Transmetallation in Electric Potential-Promoted Oxidative Coupling in a Single-Molecule Junction. CCS Chem. 2022, 4, https://doi.org/10.31635/ccschem.022.202101757.

  9. Chen-Yu Shi, Dan-Dan He, Qi Zhang, Fei Tong, Zhao-Tao Shi, He Tian, Da-Hui Qu*, Robust and Dynamic Underwater Adhesives Enabled by Catechol-Functionalized Poly(Disulfides) Network. Natl. Sci. Rev.2022, NSR_MS-2021-883.R1.

  10. Meng Chen, Da-Hui Qu*, He Tian, Dragonfly-Wing-Inspired Polymer Design for Property Enhancement. Matter 2021, 4, 2674-2676.

  11. Yue Liu, Qi Zhang, Stefano Crespi, Shao-Yu Chen, Xiu-Kang Zhang, Tian-Yi Xu, Chang-Shun Ma, Shang-Wu Zhou, Zhao-Tao Shi, He Tian, Ben L. Feringa*, Da-Hui Qu*, Motorized Macrocycle: a Photo-Responsive Host with Switchable and Stereoselective Guest Recognition. Angew. Chem. Int. Ed. 2021, 60, 16129-16138.

  12. Chen-Xi Wang, Shun-Kang Wang, Hui-Ting Yang, Yan-Xin Xiang, Xue-Bin Wang, Chun-Yan Bao*, Lin-Yong Zhu, He Tian, Da-Hui Qu*, A Light-Operated Molecular Cable Car for Gated Ion Transport. Angew. Chem. Int. Ed. 2021, 60, 14836-14840.

  13. Qi Zhang, Yuan-Xin Deng, Chen-Yu Shi, Ben L. Feringa*, He Tian, Da-Hui Qu*, Dual Closed-Loop Chemical Recycling of Synthetic Polymers by Intrinsically Reconfigurable Poly(disulfides). Matter 2021, 4, 1352-1364.

  14. Shun Yang, Cai-Xin Zhao, Stefano Crespi, Xin Li, Qi Zhang*, Zhi-Yun Zhang, Ju Mei, He Tian, Da-Hui Qu*, Reversibly Modulating a Conformation-Adaptive Fluorophore in [2]Catenane. Chem 2021, 7, 1544-1556.

  15. Zhao-Tao Shi, Yi-Xiong Hu, Zhu-Bin Hu, Qi Zhang, Shao-Yu Chen, Meng Chen, Jing-Jing Yu, Guang-Qiang Yin, Hai-Tao Sun, Lin Xu, Xiao-Peng Li, Ben L. Feringa*, Hai-Bo Yang*, Da-Hui Qu*, Visible-Light-Driven Rotation of Molecular Motors in Discrete Supramolecular Metallacycles. J. Am. Chem. Soc. 2021, 143, 442-452.

  16. Shu-Hai Qiu, Zhi-Yun Zhang, Yi-Fan Wu, Fei Tong, Kai Chen, Guo-Gang Liu, Lei Zhang, Zhao-Hui Wang, Da-Hui Qu*, He Tian, Vibratile Dihydrophenazines with Controllable Luminescence Enabled by Precise Regulation of π-Conjugated Wings. CCS Chem. 2021, 3, 2239-2248.

  17. Qi Zhang, Da-Hui Qu*, He Tian, Ben L. Feringa*, Bottom-Up: Can Supramolecular Tools Deliver Responsiveness From Molecular Motors to Macroscopic Materials? Matter,2020, 3, 355-370.

  18. Chen-Yu Shi, Qi Zhang, Chen-Yuan Yu, Si-Jia Rao, Shun Yang, He Tian, Da-Hui Qu*, An Ultrastrong and Highly Stretchable Polyurethane Elastomer Enabled by a Zipper‐Like Ring‐Sliding Effect. Adv. Mater.2020, 32, 2000345.

  19. Yuan-Xin Deng, Qi Zhang, Ben L. Feringa*, He Tian, Da-Hui Qu*, Toughening a Self-Healable Supramolecular Polymer by Ionic Cluster-Enhanced Iron-Carboxylate Complexes. Angew. Chem., Int. Ed.2020, 59, 5278-5283.

  20. Qian Wang, Qi Zhang, Qi-Wei Zhang, Xin Li, Cai-Xin Zhao, Tian-Yi Xu, Da-Hui Qu*, He Tian, Color-Tunable Single-Fluorophore Supramolecular System with Assembly-Encoded Emission. Nat. Commun.2020, 11, 158.

  21. Qi Zhang, Yuan-Xin Deng, Hong-Xi Luo, Chen-Yu Shi, Geoffrey M. Geise, Ben L. Feringa*, He Tian, Da-Hui Qu*, Assembling a Natural Small Molecule into a Supramolecular Network with High Structural Order and Dynamic Functions. J. Am. Chem. Soc.2019,141, 12804−12814.

  22. Su-Jun Chen, Yi-Chuan Wang, Ting Nie, Chun-Yan Bao*, Chen-Xi Wang, Tian-Yi Xu, Qiu-Ning Lin, Da-Hui Qu*, Xue-Qing Gong, Yi Yang, Lin-Yong Zhu*, He Tian, An Artificial Molecular Shuttle Operates in Lipid Bilayers for Ion Transport. J. Am. Chem. Soc.2018, 140, 17992-17998.

  23. Zhang Q, Rao-Si Jia, Tao Xie,Xin Li, Tian-Yi Xu, Da-Wei Li, Da-Hui Qu*, Yi-Tao Long, He Tian*, Muscle-Like Artificial Molecular Actuators for Nanoparticles. Chem2018,4, 2670-2684.

  24. Qi Zhang, Chen-Yu Shi, Da-Hui Qu*, Yi-Tao Long, Ben L. Feringa*, He Tian*, Exploring a Naturally Tailored Small Molecule for Stretchable, Self-Healing and Adhesive Supramolecular Polymers. Sci. Adv.2018,4, 8192-8199.

  25. Qi Zhang, Wen-Zhi Wang, Jing-Jing Yu, Da-Hui Qu*, He Tian, Dynamic Self‐Assembly Encodes A Tri‐stable Au–TiO2 Photocatalyst.Adv. Mater.2017,29, 1604948.