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韩建伟

韩建伟博士,1980 年出生于山东平度。化学与分子工程学院精细化工系副教授

招生专业: 应用化学;欢迎感兴趣的研究生同学联系交流

联系地址:实验六楼100 & 101

电话:021-64253040

电邮:jianweihan@ecust.edu.cn

  

ORCIDhttp://orcid.org/0000-0002-8354-5684

科研个人主页:https://hanjianweixiaozu.wordpress.com/


2002年于山东理工大学化学工程系本科毕业,论文指导教师:傅忠君教授;2005年获华东理工大学应用化学专业工学硕士学位,师从王利民教授,田禾院士;2009年在德国亚琛工业大学获得自然科学博士学位(Dr. rer. nat., 导师 Dieter Enders教授。其中,20052-7月在上海药明康德公司任新药研发研究员; 2009-2011年在日本京都大学丸岗啓二(Keiji Maruoka教授)教授课题组做博士后研究; 20115-201611月回国后,中国科学院上海有机化学研究所,沪港联合合成实验室黄乃正院士(Henry N. C. Wong 教授)科研团队任副研究员。201611月起,华东理工大学,化学与分子工程学院,精细化工系任副教授。迄今在国际学术期刊上发表研究论文四十余篇;研究论文总引用数1500余次。获得过2007年度上海市优秀研究成果奖(沪教委高[2007]74)2005-2008年《Tetrahedron》杂志最高引用率奖;2014年度德国 Thieme Chemistry Journals Award

研究兴趣:香气持久缓释与有害有机挥发物(VOC)释放控制、设计新催化剂在不对称催化中的应用和探索新反应性合成功能分子。

Jian-Wei Han, was born at Shan-dong, China in 1980. He graduated from Shandong University of Technology in 2002, and obtained his Master Degree from East China University of Science and Technology under the mentorship of Professors Li-Min Wang and He Tian in 2005. He then received his Ph.D. degree under the supervision of Professor Dieter Enders at Rheinisch-Westfälische Technische Hochschule (RWTH) Aachen (Germany) in 2008. After two years postdoctoral research at Kyoto University (Japan) with Professor Keiji Maruoka, he moved to Shanghai Institute of Organic Chemistry, the Chinese Academy of Sciences as an Associate Professor in 2011. From 2016, he was appointed associate professor at School of Chemistry & Molecular Engineering, East China University of Science and Technolog. He is a recipient of Thieme Chemistry Journals Award (2014). His research interests are design and synthesis of new catalysts in asymmetric transformations, exploration of novel reactivity of organic molecules and the preparation of functional materials. So far he has published more than 40 peer-reviewed papers.

  

主要科研项目:

  1. 2013.01-2015.12,国家自然科学青年基金项目,No.21202186: 基于四苯并环辛四烯骨架设计合成手性Brønsted 酸碱催化剂及其在不对称催化中的应用研究,(25万,项目负责人)。

  2. 2015.01-2018.12,国家自然科学基金面上项目,No. 21472213: 手性磷螺环超强碱分子催化不对称芳基化反应方法学的研究,85万,项目负责人)。

  3. 2017.01-2022.12,国家重点研发计划重点专项,芳香纳米材料制备与应用研究 (参与)。

  4. 2012.08-2014.07, 裘槎基金会资助研究项目, 基于TetraphenyleneSIOCPhox发展不对称催化方法学及其应用于天然产物Dhilirolide DIsocedrene类衍生物的全合成研究 (100万, Co.PI)。

  5. 2016.08-2018.07,裘槎基金会资助研究项目, 过渡金属催化烯丙基化反应和磷腈小分子催化加成反应的选择性研究(100万, Co.PI)。

  6. 2012.08-2015.07,中国科学院国际合作局港澳台合作重点项目一项(20万,主要参与人)。

  

论文发表:

  1. Huangguan Chen, Jianwei Han,* Limin Wang* Diels–Alder cycloadditions of N-arylpyrroles via aryne intermediates using diaryliodonium salts. Beilstein J. Org. Chem.2018, 14, 354. (Invited by T. Wirth for Special Issue of hypervalent iodine chemistry)

  2. Xunshen Wu, Jianwei Han,* Limin Wang* Palladium Catalyzed C–I and Vicinal C–H Dual Activation of Diaryliodonium Salts for Diarylations: Synthesis of Triphenylenes. J. Org. Chem.2018, 83, 49.

  3. Guo-Li Chai, Jian-Wei Han, Henry N. C. Wong* Asymmetric Darzens Reaction of Isatins with Diazoacetamides Catalyzed by Chiral BINOL–Titanium Complex. J. Org. Chem.201782, 12647.

  4. Xin Li, Jian-Wei Han, Yan-Xia Zhang, Henry N.C. Wong* Palladium-Catalyzed Double Suzuki Reactions: Synthesis of Dibenzo[4,5:6,7]cyclohepta [1,2,3-de]naphthalenes. Asian J. Org. Chem.2017, 6, 1876.

  5. Jianwei Han,* Xunshen Wu, Zhiang Zhang, Limin Wang* Palladium-Catalyzed Arylation/Cyclization /Desulfonation Cascades toward 4-Aryl Quinolin-2(1H)-ones with Diaryliodonium Salts. Tetrahedron Lett. 2017, 58, 3433.

  6. Jianwei Han,* Xiaofei Qian, Bowen Xu, Limin Wang* Potassium tert-Butoxide Mediated Arylation of 2-Substituted Malononitriles Using Diaryliodonium Salts. Synlett2017,28, 2139.

  7. Jian-wei Han*, Xiao-shui Peng, Henry N. C. Wong*. Synthesis of Tetraphenylene Derivatives and Their Recent Advances” Natl. Sci. Rev. 2017, 4, 892.

  8. Guo-Li Chai, Jian-Wei Han, Henry N. C. Wong* Hydroxytetraphenylenes as Chiral Ligands: Application to Asymmetric Darzens Reaction of Diazoacetamide with Aldehydes. Synthesis 2017, 49, 181. (Invited by P. Knochel for Special Issue for Prof. Dr. Dieter Enders on the occasion of his 70th birthday)

  9. Xiaofei Qian, Jianwei Han,* Limin Wang* tert-Butoxide-Mediated Mediated Cascade Desulfonylation/arylation/hydrolysis of Cyclic Sulfonyimines Using Diaryliodonium Salts: Synthesis of Diaryl Ether Derivatives Bearing a 2-Aldehyde Group. RSC Adv. 2016, 6, 89234.

  10. Song Mao,Zerui Hua,Xunshen Wu,Yang Yang,Jianwei Han,Limin Wang*Tandem Arylation/Friedel-Crafts Reaction of O-Hydroxy Bisbenzylic Alcohols with Diaryliodonium Salts: One Pot Synthesis of Unsymmetrical 9-Arylxanthenes. ChemistrySelect20161, 403.

  11. Xing Gao, Jianwei Han,* Limin Wang* Tartrate-derived iminophosphorane catalyzed asymmetric hydroxymethylation of 3-substituted oxindoles with paraformaldehyde. Org. Chem. Front.2016, 3, 656. (封面文章)

  12. Xing Gao, Jianwei Han,* Limin Wang* Chiral Iminophosphoranes Organocatalyzed Asymmetric Sulfenylation of 3-Substituted Oxindoles: Substrate-interrelated Enantioselectivities. Synthesis 2016, 48, 2603.(Invited by E. M. Carreira for Special Topic of Asymmetric Synthesis; Dedicated to Prof. Dr. Dieter Enders on the occasion of his 70th birthday).

  13. Xiaofei Qian, Jianwei Han,* Limin Wang* tert-Butoxide-Mediated Arylation of 2-Substituted Cyanoacetates with Diaryliodonium Salts. Adv. Synth. Catal.2016, 358, 940.

  14. Xiaofei Qian, Jianwei Han,* Limin Wang* Copper-catalyzed selective ortho-arylations of 2-naphthol and phenol derivatives with diaryliodonium salts. Tetrahedron Lett.2016, 57, 607.

  15. Yanxia Zhang,Jianwei Han*, Zhenjiang Liu* Palladium Catalyzed Double Suzuki-Miyaura Reactions Using Cyclic Dibenziodoniums: Synthesis of ortho-Tetraaryls. J. Org. Chem. 2016,81, 1317. (Selected as Featured Article, 封面文章;编辑优选文章;文章免费阅读进行推介).

  16. Xin Li, Jian-Wei Han, Henry N.C. Wong* Palladium-Catalyzed Double Ullmann Reaction: An Approach towards Tetraphenylenes. Asian J. Org. Chem.2016, 5, 74. (封面文章)

  17. Xunshen Wu, Yang Yang, Jianwei Han*, Limin Wang* Palladium Catalyzed C–I and Vicinal C–H Dual Activation of Diaryliodonium Salts for Diarylation: Synthesis of 4,5-Benzocoumarins. Org. Lett. 2015, 17, 5654.

  18. Yanxia Zhang, Jianwei Han*, Zhenjiang Liu* tert-Butoxide-Mediated Arylation of 1-Acetylindolin-3-ones with Diaryliodonium Salts. Synlett2015, 26, 2593.

  19. Xing Gao, Jianwei Han*, Limin Wang* Design of Highly Stable Iminophosphoranes as Recyclable Organocatalysts: Application to Asymmetric Chlorinations of Oxindoles. Org. Lett.2015, 17, 4596.

  20. Jing-Xing Chen, Jian-Wei Han, and Henry N. C. Wong* Synthesis and Chiroptical Properties of Double-Helical (M)- and (P)-o-Oligophenylenes. Org. Lett. 2015, 17, 4296.

  21. Yang Yang, Jianwei Han*, XunShen Wu, Shujia Xu, Limin Wang* Synthesis of 4-arylcoumarins via palladium-catalyzed arylation/cyclization of ortho-hydroxylcinnamates with diaryliodonium salts.  Tetrahedron Lett.2015, 56, 3809.

  22. Yanxia, Zhang, Jianwei Han*, Zhenjiang Liu* Diaryliodonium salts as efficient Lewis acid catalysts for direct three component Mannich reactions. RSC Adv.2015, 5, 25485.

  23. Jian-Wei Han*, Xin Li, Henry N. C. Wong* Our Expedition in Eight-Membered Ring Compounds: From Planar Dehydrocyclooctenes to Tub-Shaped Chiral Tetraphenylenes. Chem. Rec.2015, 15, 107.

  24. Xiang-Yin TianJian-Wei Han, Qiong Zhao, Henry N. C. Wong* Asymmetric Synthesis of 3,3,5,5-Tetrasubstituted 1,2-Dioxolanes: Total Synthesis of Epiplakinic Acid F. Org. Biomol. Chem.2014, 12, 3686.

  25. Yang Yang, Xunshen Wu, Jianwei Han*, Song Mao, Xiaofei Qian, Limin Wang* Cesium Carbonate Promoted Direct Arylation of Hydroxylamines and Oximes with Diaryliodonium Salts. Eur. J. Org. Chem.2014, 6854.

  26. Yang Yang, Jianwei Han*, Xunshen Wu, Song Mao, Jianjun Yu, Limin Wang* Copper-Catalyzed Diarylation of Activated Alkenes with Diaryliodonium Salts. Synlett2014, 25, 1419.

  27. Shengying Wu, Jun Tang, Jianwei Han*, Dan Mao, Xin Liu, Xing Gao, Jianjun Yu, Limin Wang* Design of C2-symmetric Salen Ligands and Their Co(II)- or Yb(III)-complexes, and Their Role in the Reversal of Enantioselectivity in the Asymmetric Henry Reaction. Tetrahedron2014, 70, 5986.

  28. Xu Geng, Song Mao, Liangshun Chen, Jianjun Yu, Jianwei Han, Jianli Hua, Limin Wang* Copper-catalyzed Direct N-arylation of N-arylsulfonamides Using Diaryliodonium Salts in Water. Tetrahedron Lett. 2014, 55, 3856.

  29. Jian-wei Han,* Jing-xing Chen, Xin, Li, Xiao-shui Peng, Henry N. C. Wong* Recent Developments and Applications of Chiral Tetraphenylenes. Synlett2013, 24, 2103.

  30. Song Mao, Fenglou Guo, Juan Li, Xu Geng, Jianjun Yu, Jianwei Han, Limin Wang* Copper-Catalyzed Direct N-Arylation of Naphthalimides Using Diaryliodonium Salts Synlett2013, 24, 1959. Fenglou Guo, Jianwei Han,* Song Mao, Juan Li, Xu Geng, Jianjun Yu, Limin Wang* DirectC-arylation of Polyfluoroarenes with Diaryliodonium Salts via Pd(OAc)2-catalysis. RSC Adv.2013, 3, 6267. Jianwei Han*Eco-Catalysis Leads the Way to Green Synthetic Chemistry. Org. Chem. Curr. Res. 2012, 2161-e401. (Invited Paper)

  31. Jianfang Cui, Chao Cheng, Xiang Gao, Zongwei Cai, Jianwei Han, Henry N. C. Wong* 2,3,10,11-Tetrahydroxytetraphenylene and its Application in Molecular Recognition. Helv. Chim. Acta. 2012, 95, 2604.

  32. Fenglou Guo, Limin Wang*, Peiqi Wang, Jianjun Yu, Jianwei Han* Transition-Metal-Free N-Arylation of Carbazoles and C-Arylation of Tetrahydrocarbazoles by using Diaryliodonium Salts. Asian J. Org. Chem. 2012, 1, 218. (Highlighted in Angewandte Spotlights, Angew. Chem. Int. Ed.2012, 51, 10926-10928; Most cited paper in 2012, AsianJOC. )

  33. Fenglou Guo, Limin Wang*, Song Mao, Chi Zhang, Jianjun Yu, Jianwei Han* Cationic bromonium complex: NBS/P(OPh)3 as an efficient catalyst for Nazarov cyclization.Tetrahedron 2012, 68, 8367.

    研究生和博士后阶段论文发表:

  34. Shin Moteki (Assi. Prof.),Jianwei Han, Satoru Arimitsu, Matsujiro Akakura, Keiji Nakayama, Keiji Maruoka* An Achiral-Acid-Induced Switch in the Enantioselectivity of a Chiral cis-Diamine-Based Organocatalyst for Asymmetric Aldol and Mannich Reactions. Angew. Chem., Int. Ed. 2012, 51, 1187. (Times Cited: 56, ISI)

  35. Dieter Enders*, Jianwei Han Synthesis of enantiopure triazolium salts from pyroglutamic acid and their evaluation in the benzoin condensation. Tetrahedron, Asymmetry 2008. 19, 1367. (Times Cited: 89, ISI)

  36. Dieter Enders*, Jianwei Han, Alexander Henseler Asymmetric Intermolecular Stetter Reactions Catalyzed by a Novel Triazolium Derived N-heterocyclic Carbene. Chem. Commum.2008, 3989. (Highlight by SYNFACTS, 2008, 10, 1099. Times Cited:120, ISI).

  37. Dieter Enders*, Jianwei Han Asymmetric Intermolecular Stetter Reactions of Aromatic Heterocyclic Aldehydes with Arylidenemalonates. Synthesis, 2008, 3864. (Times Cited: 49, ISI)

  38. Limin Wang*, Jianwei Han, Jia Sheng, Zhaoyu Fan, He Tian Yb(OTf) 3 Catalyzed Mannich Reaction of Ketones with Aromatic Aldehydes and Aromatic Amines: Three -component 'One-pot' Synthesis of b-amino Ketone Derivatives. Chin. J. Org . Chem.(有机化学)2005, 25, 591. (Times Cited: 33, ISI)

  39. Limin Wang*, Jianwei Han, Jia Sheng, Zhaoyu Fan, He Tian, Xiaoping Tang Rare Earth Perfluorooctanoate [RE(PFO)3]-Catalyzed Condensations of Indole with Carbonyl Compounds. Synlett,2005, 337. (Times Cited: 130, ISI)

  40. Limin Wang*, Jianwei Han, Jia Sheng, Zhaoyu Fan, He Tian Lanthanum perfluorooctanoate catalyzed facile one-pot Mannich reaction: Three Component Synthesis of b-Amino Carbonyl Compounds. Catal. Comm.2005, 6, 201. (Times Cited: 87, ISI)

  41. Limin Wang*, Jia Sheng, Liang Zhang, Jianwei Han, Zhaoyu Fan, He Tian Facial Yb(OTf)3 Promoted One-Pot Synthesis of Polyhydroquinoline Derivatives Through Hantzsch Reaction. Tetrahedron,2005, 61, 1539. (Times Cited: 288, ISI)

  42. Limin Wang*, Jia Sheng, Liang Zhang, Jianwei Han, Zhaoyu Fan, He Tian Yb(OTf)3 Catalyzed Knoevenagel Reaction of Methylene Compounds with Aldehydes under Solvent-free Condition. Chin. J. Org . Chem.(有机化学)2005, 25, 964. (Times Cited: 9, ISI)

  43. Limin Wang*, Jia Sheng, Jianwei Han, Zhaoyu Fan, He Tian, ChangTao QianA ConvenientSynthesisofα,α'-Bis(substitutedbenzylidene)-cycloalkanonesCatalyzedby Yb(OTf)3 Under Solvent-Free Conditions. Synthesis. 2004, 3060. (Times Cited: 77, ISI)

    专利:

    1) 王利民, 韩建伟,樊兆玉,田禾,盛佳,含稀土金属的全氟羧酸路易酸催化剂及其制备方法, 2007.3, 中国, ZL 200410024683. 0.

    2) 韩建伟,高省,黄乃正,基于手性二胺的螺环骨架的手性磷腈催化剂,制备方法及其应用,2015.8, 中国,ZL 201510495960.4.


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